The activity of a radioactive substance is measured every 200 s by means of a Geiger counter. The results are as follows.
Time/s | 0 | 200 | 400 | 600 |
Count | 1600 | 802 | 399 | 205 |
a. ∇N = √N = √1600 = 40.0
b. The count rate is 1600 counts / 10s = 160 count/s.
c. The activity decreases by half every 200 s do the half-life is 200 s
d. Activity = ∇n = 0.693T1/2 = 0.693 × 106 / 200 S = 3465 Bq
Pesticides can travel great distances through the environment. When sprayed on crops or in gardens, pesticides can be blown by the wind to other areas. They can also flow with rain water into nearby streams or can sleep through the soil into ground water.
Some pesticides can remain in the environment for many years and pass from one organism to another. The figure below shows the amount of pesticide in ppm at different levels in a food chain.
1.
a. producers
0.08 = 4
0.02.
b. herbivorous fish
20 = 1,000
0.02
c. predatory fish
60 = 3,000
0.02
d. hawk
90 = 4,500
0.02
2. The concentration factor keeps increasing and larger and
larger as you move up and as such it can be concluded that it is
a persistence chemical it is not easily broken down it is stored rather
than metabolising that is why it keeps getting a higher and higher concentration.
3. 4th trophic level (Top carnivore)
4. 4th trophic level
A projectile is fired horizontally from the top of a 20.0 m high cliff.
a. suppose the speed is u and the fall time is t ; then ut = 200 m.
the time to fall h = 20 m from rest is t = √2h/g = 2.00 s so u = 200.0 m / (2.00 s) = 0.100 kms-1
b. the vertical component of the velocity at the foot of the cliff
vy = uy + gt = 10m s-2 × 2 s = 20.0 m s-1
(or vy = √2gh = 20.0 m s-1) whereas the horizontal component is the firing speed. So the speed at the foot of the cliff
V = √v 2/x + v 2/y = √(100. M s-1)2 + (20.0 m s-1)2
= 102 m s-1
c. The impulse on the impact has a magnitude | = mv = 0.100kg × 02 m s-1 = 10.2N s
so the average stopping force is |/t = 2.04 N
a. Logxn = nlogx = np
b. Logx, logx2, logx3,…,… are simply p, 2p, 3p, 4p, … a linear sequence with first term a=p and arithmetic difference d = p
c. Logx + logx2 + logx3 + …+ logx10 = p + 2p + 3p + 5p + . . . + 10p
=p(1 + 2 + 3 + . . . + 10)
=p(10/2)(1 + 10) = 55p
Hence k = 55
An acid of phosphorus HXPYOZ contains 47.0% phosphorus, and 4.5% hydrogen. Determine the empirical formula of the acid
H = 1.0, O = 16.0, P = 31.0
View Answer
With phenolphthalein, the reaction in the titration is as follows;
HCI + Na2Ca3 → NaHCO3 + NaCl
Molar mass of Na2Ca3 = 46 +12 + 48 = 106
Moles of Na2Ca3 weighed = 0.106/106 = 0.001 mmole of Na2Ca3 weighed = 1.0
Since HCI and Na2Ca3 react in a 1:1 ratio, mmole of HCI used = 1.0
But mmole = moldm-3 × V in cm3
Therefore, concentration of HCI = 1.0 mmol/20 cm3
= 0.050 moldm-3
You have been provided with the following materials:
1. The pot containing the small watered plant is covered up to the base of the stem with the plastic sheet to prevent evaporation.
2. The pot is cut across the stem just above the soil level with the knife
3. The glass tubing is attached to the cut end of the stem using the rubber tubing.
4. The eosin solution is poured into the glass tube and the level is marked.
5. The setup is left for several hours after which the final level of the eosin solution is measured.
6. The difference between the first level and the final level of the eosin solution gives the column of water supported by the root pressure.
The van der Waals equation of state for n moles of gas at pressure p, volume v, and temperature T is given as (p + n2a/v)(v/n - b) = RT or as (p + n2a/v2)(v - nb) = Nrt
a) The parameter a accounts for interactions between the molecules of the gas.
The parameter b accounts for non-zero volume of the molecules of the gas.
b) R is the universal gas constant
(R = NAkB = 8.314 J K-1 mol-1).
c) i) Substitute the given values of the parameters to obtain
T = ( p + n2 a/V2) (V/n - b) / R
= (140000 Pa + (2 mol)2 × 4.17 J m3 / (0.025 m3)2) × (0.025 m3 / 2 mol – 3.71 × 10-5 m3 mol-1)
/ 8.314 J K-1 mol-1 = 250 K
ii) An ideal gas at the same volume and pressure will have a temperature of Pv / nR = 210 K.
The solar constant, the mean intensity on the earth's surface of radiation from the sun, is 1000 W m-2. A solar power installation comprises five solar panels with a conversion efficiency of 20% installed in such a manner that each panel measuring, 2 m long and 1 m wide, can receive direct sunlight.
a) Maximum power density equals solar constant times efficiency, that is, 200 W ms-2.
b) Each panel has 2 m2, so each panel can give 400 W. all five can give 2000W.
c) Maximum energy the installation can deliver in 2 h is the product of power and time, which is 2000 W × 7200 s = 14400 kJ.
A parcel of land is rectangular and measures 300 m long and 250 m wide. A perimeter wall 2 m high is to be built using concrete bricks of width 20 cm and density 2500 kg m-3 .
a. The perimeter of a rectangle is twice the sum of its length and breadth, giving 1100m.
b. The volume of the wall equals its perimeter times its height times its thickness, that is, 1100 m × 2 m × 0.2 m = 440 m3 ;
so its mass, given by its density multiplied by its volume, is 1.1 × 106 kg.
c. Pressure equals weight of wall divided by base area:
P = F/A =mg/A = 1.1 × 106 kg × 10 ms2 / ( 1100 m × 0.2 m) = 50 000 Nm-2
A potted plant was watered and the pot enclosed in a plastic bag. A rubber band was used to tie the bag securely round the base of the stem. The plant was weighed at 7am and at 5pm. During this time it lost 40g in mass.
M = 40g, t = 17hr -7hr, t = 10hr
View Answer
a. The plant lost 40g in 10 hours, so its rate of transpiration was 40/10 = 4g per hour.
b. I) in daylight, the mass loss due to transpiration will be reduced by a gain in mass resulting from photosynthesis.
ii) In darkness some of the decrease in mass will be due to the loss of water and carbon dioxide produced by respiration
c. If the plant had been short of water, this might have restricted the rate of transpiration.
d. The plastic bag prevented evaporation taking place from the pot or the soil. Had this evaporation not been prevented, the mass loss could not have been attributed solely to transpiration.
An experiment was performed to investigate Graham's law of diffusion. For this experiment, samples of the following gases were assembled: Hydrogen, helium, neon, argon, ammonia and bromine.
The rate of diffusion of neon was determined first and was found to be X ms-1.
The temperature and pressure were kept constant throughout the experiment.
Calculate the anticipated rates of diffusion of the rest of the gases relative to that of neon.
H = 1.0; He = 4.0; Ne = 20.0; Ar = 40.0; Br = 80.0; N = 14.0
View Answer
Graham's law; rate is proportional to 1/√(molar mass)
Therefore R2/R1 = √(M1 /M2); and
R2 = R1 √(M1 /M2)
Where R1 and M1 are the rate and molar mass of gas-1 respectively and R3 and M2 for gas-2
(1) For hydrogen gas, M = 2
RH2 = X√(20 /2) = X√10
(2) For Helium; RHe = X√(20 /4) = X√5
(3) For argon; RAr = X√(20 /40) = X/√2
(4) For bromine; RBr = X√(20 /160) = X/2√2
(5) For ammonia; RNH3 = X√(20 /17) = X√(20/17)
The traits in certain race of mammals are described below. Use your knowledge in genetics to complete the worksheet.
Trait | Dominant | Recessive gene |
Body Size | Muscular (M) | Skinny (m) |
Body Colour | Dark (D) | Yellow (d) |
Eye Shape | Round (R) | Oval (r) |
Nose type | Long (L) | Stubby (i) |
i.
1. LL – Long nose
2. Dd – Dark body
3. Mm – Muscular body
4. RR – Round eye
5. Rr – Round eye
6. II - Stubby nose
7. MM - Muscular body
8. DD - Dark body
ii. Write the genotypes for each of the following
k. Yellow body – dd
l. Skinny body – mm
m. Oval eyes – rr
n. Long nose – LL and LI
o. Stubby nose – II
p. Round eyes – RR and Rr
q. Muscular body – MM and Mm
r. Dark body - DD and Dd
s. Heterozygous round eyes - Rr
t. Homozygous long nose - LL
Given that (1 + kx)6 = 1 + 12x + px2 + qx3 + …., Find the values of
(1 + kx)6 = 1 + 6(kx) + 15(kx)2 + 20(kx)3 + ….
(Pascal's triangle)
= 1 + 12x + px2 + qx3 + …
Comparing coefficients
i) For x, 6k = 12, hence k =2
ii) For x2, 15k2 = p, hence p = 15(4) = 60
iii) For x3, 20k3 = q, hence q = 20(8) = 180
iv) The term in x4 is 15(kx)4 = 15(2)4x4
The coefficient of x4 = 15(16) = 240
Three masses, m1, m2 and m3 , on a horizontal frictionless surface are connected by inextensible strings so that m1 is connected to m2 and m2 is connected to m3. A horizontal force F pulls on mass m1 . Find the tension in each of the strings.
View Answer
The total mass is M = m1 + m2 + m3 and the acceleration of each of them is a=F/M. The only forces acting on m3 is the tension T1 in the string attaching it to m2 so, by Newton's second law,
m3a = T1 = m3F / (m1 + m2 + m3).
The forces acting on m2 are the tension T1 in the string connecting it to m1 and
the tension T1 in the string connecting it to m3. By Newton's second law,
T2 – T1 = m2a + T1 = (m2 + m3)a = (m2 + m3) F / (m1 + m2 + m3)
The equation of a curve is given by y = x3 – 27x.
Find:
a) Y = x3 – 27x (stationary points) dy/dx = 3x2 – 27 = 0
X2 – 9 = 0, x = ±3
For x = 3, y = 33- 27(3) = 27 – 81 = -54
i.e. (3, -54) (stationary point)
for x = -3, y = -27 + 81 = 54,
i.e.(-3, 54) (stationary point)
d2y/dx2 = 6x,
for x = 3, d2y/dx2 = 3(6) = 18 > 0,
hence (3, -54) is a minimum point.
For x = -3, d2y/dx2 = 6(-3) = -18 < 0.
Hence (-3, 54) is a maximum point.
b. point of inflexion
d2y/dx2 = 6x = 0, hence x = 0
for x = 0, y = 0, hence point of inflexion is (0, 0)
Consider the following enthalpies of formation given in kJmol-1
C6H6(I) 49.0; CO2(g) -394.0; H2O(g) -242.0
Use the data given to calculate the enthalpy change for the combustion of mole of benzene.
View Answer
C6H6 + 7½O2 ⟶ 6 CO2 + 3 H2O
Δ H combustion = Σ ΔHf(products) − Σ ΔHf(reactants)
= (−6 × 394− 3 × 242) − 49 = (− 2364 − 726) − 49
= −3139 or −3.14×103 kJmol-1
In order to determine the concentration of an HCI solution, 0.1060 g of anhydrous Na2CO3 was weighed and dissolved in some deionized water. When the whole solution was titrated against HCI using phenolphthalein as indicator, the titre was 20.0 cm3. Use this information to determine the concentration of the HCI solution.
Na = 23.0; O = 16.0; C = 12.0
View Answer
With phenolphthalein, the reaction in the titration is as follows;
HCI + Na2Ca3 ⟶ NaHCO3 + NaCl
Molar mass of Na2Ca3 = 46 + 12 + 48 = 106
Moles of Na2Ca3 weighed = 0.106/106 = 0.001 mmole of Na2Ca3 weighed = 1.0
Since HCI and Na2Ca3 react in a 1:1 ratio, mmole of HCI used = 1.0
But mmole = moldm-3 × V in cm3
Therefore, concentration of HCI = 1.0 mmol/20 cm3
= 0.050 moldm-3
The diagram below represents a simplified water cycle. Use it to answer the following questions.